Heteropolynuclear PdAg4 complexes with self-assembled trans-chelating {(Ar2pz)3Ag2} units

Kana Kinoshita; Yiming Yang; Shiho Nagano; Shinnosuke Horiuchi; Yoshihide Nakao; Kenichiro Omoto; Eri Sakuda; Yasuhiro Arikawa; Keisuke Umakoshi

doi:10.1039/D5DT01078K

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Heteropolynuclear PdAg₄ complexes with self-assembled trans-chelating {(Ar₂pz)₃Ag₂} units†

Kana Kinoshita,^a Yiming Yang,^a Shiho Nagano,^a Shinnosuke Horiuchi,

*^ab Yoshihide Nakao,

^c Kenichiro Omoto,

^a Eri Sakuda,

^a Yasuhiro Arikawa

^a and Keisuke Umakoshi

*^a

Author affiliations

* Corresponding authors

^a Division of Chemistry and Materials Science, Graduate School of Engineering, Nagasaki University, 1-14 Bunkyo-machi, Nagasaki, Japan
E-mail: shoriuchi@g.ecc.u-tokyo.ac.jp, kumks@nagasaki-u.ac.jp

^b Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902, Japan

^c Department of Life Science, Faculty of Life Science, Kyushu Sangyo University, 2-3-1 Matsukadai, Higashi-ku, Fukuoka 813-8503, Japan

Abstract

Herein, we report novel square-planar Pd(II) complexes bearing two Ag₂(Ar₂pz)₃ units as self-assembled trans-chelating ligands. This structural motif is unique to Pd(II) ions and cannot be obtained from a Pt(II) metal source owing to the stronger dative bonding nature of the Pt(II) ion compared to that of the Pd(II) ion.

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Article information

DOI: https://doi.org/10.1039/D5DT01078K
Article type: Communication
Submitted: 07 May 2025
Accepted: 19 May 2025
First published: 21 May 2025

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Dalton Trans., 2025,54, 9140-9144

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Heteropolynuclear PdAg₄ complexes with self-assembled trans-chelating {(Ar₂pz)₃Ag₂} units

K. Kinoshita, Y. Yang, S. Nagano, S. Horiuchi, Y. Nakao, K. Omoto, E. Sakuda, Y. Arikawa and K. Umakoshi, Dalton Trans., 2025, 54, 9140 DOI: 10.1039/D5DT01078K

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