Stereoisomers of metal–organic dimers induced by the steric constraint of dissymmetric terpyridine ligands

Jianjun Ma; Hao Yu; Ning Zhang; Junjuan Shi; Jiaqi Li; Kehuan Li; Ningxu Han; Houyu Zhang; Junmin Chang; Ming Wang

doi:10.1039/D5DT00948K

Stereoisomers of metal–organic dimers induced by the steric constraint of dissymmetric terpyridine ligands†

Jianjun Ma,^a Hao Yu,^b Ning Zhang,^c Junjuan Shi,^b Jiaqi Li,^b Kehuan Li,^b Ningxu Han,

^b Houyu Zhang,

^b Junmin Chang*^a and Ming Wang

*^b

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* Corresponding authors

^a The Xinjiang Key Laboratory of Natural Medicine Active Components and Drug Release Technology, College of Pharmacy, Xinjiang Medical University, Urumqi, Xinjiang 830011, China
E-mail: 1617265908@qq.com

^b State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, Jilin 130012, China
E-mail: mingwang358@jlu.edu.cn

^c Jilin Province Product Quality Supervision and Inspection Institute, Changchun 130103, China

Abstract

Herein, we report a novel molecular design strategy for constructing stereoisomers based on dissymmetric modified ligands and closely packed dimeric structures. X-ray analyses reveal that different substituents have an important effect on stereoisomers and can provide various driving forces to realize the adjustment of crystal packing.

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Stereoisomers of metal–organic dimers induced by the steric constraint of dissymmetric terpyridine ligands†

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Stereoisomers of metal–organic dimers induced by the steric constraint of dissymmetric terpyridine ligands

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