Ionic porous organic polymer as a bifunctional platform for CO2 photoreduction and proton conduction

Jun-Rui Liu; Yao-Mei Fu; Wen-Tao Ju; Meng Lian; Teng Liu; Xing Meng; Hai-Ning Wang; Zhong-Min Su

doi:10.1039/D4DT03493G

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Ionic porous organic polymer as a bifunctional platform for CO₂ photoreduction and proton conduction†

Jun-Rui Liu,^a Yao-Mei Fu,^b Wen-Tao Ju,^a Meng Lian,^a Teng Liu,^a Xing Meng,

*^a Hai-Ning Wang

*^a and Zhong-Min Su

^bc

Author affiliations

* Corresponding authors

^a School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo 255049, China
E-mail: mengxing837@foxmail.com

^b Shandong Engineering Research Center of Green and High-value Marine Fine Chemical; Weifang University of Science and Technology, Shouguang, China

^c Jilin University, Institute of Theoretical Chemistry, State Key Laboratory of Supramolecular Structure and Materials, Changchun 130021, China

Abstract

To unveil the potential of ionic porous organic polymers, the ion-exchanged sample POP–BPy–PMV was synthesized, exhibiting a CO generation rate of 22.75 μmol g⁻¹ h⁻¹. Additionally, the original POP–BPy displayed a high proton conductivity of 1.18 × 10⁻² S cm⁻¹ under 100% humidity at 90 °C.

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Article information

DOI: https://doi.org/10.1039/D4DT03493G
Article type: Communication
Submitted: 19 Dec 2024
Accepted: 04 Apr 2025
First published: 22 Apr 2025

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Dalton Trans., 2025, Advance Article

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Ionic porous organic polymer as a bifunctional platform for CO₂ photoreduction and proton conduction

J. Liu, Y. Fu, W. Ju, M. Lian, T. Liu, X. Meng, H. Wang and Z. Su, Dalton Trans., 2025, Advance Article , DOI: 10.1039/D4DT03493G

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