Issue 12, 2025
From the journal:

Catalysis Science & Technology

CoFe-LDHs catalyzed oxidation cleavage of terminal alkenes to aldehydes or ketones†

Jun Li,a   Shijie Shen,a   Yuge Li,a   Guo-Jun Deng ORCID logo a  and  Fuhong Xiao ORCID logo *a  

* Corresponding authors

a Key Laboratory for Green Organic Synthesis and Application of Hunan Province, Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105, China
E-mail: fhxiao@xtu.edu.cn
Fax: (+86)0731 5829 2251
Tel: (+86)0731 5829 8601

Abstract

Cobalt–iron layered double hydroxides (CoFe-LDHs) with adjustable Co/Fe ratios were synthesized for the alkene oxidative cleavage to carbonyls under 1 atm O2. Structural analyses reveal that coexisting Co2+/Co3+ species enhance catalytic activity, while synergistic Co–Fe interactions in the LDH lattice promote electron transfer, achieving superior conversion and selectivity compared to monometallic catalysts.

Graphical abstract: CoFe-LDHs catalyzed oxidation cleavage of terminal alkenes to aldehydes or ketones

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D5CY00453E
Article type
Communication
Submitted
12 Apr 2025
Accepted
15 May 2025
First published
15 May 2025

Catal. Sci. Technol., 2025,15, 3528-3535

Permissions

Request permissions

CoFe-LDHs catalyzed oxidation cleavage of terminal alkenes to aldehydes or ketones

J. Li, S. Shen, Y. Li, G. Deng and F. Xiao, Catal. Sci. Technol., 2025, 15, 3528 DOI: 10.1039/D5CY00453E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements