CO2 hydrogenation to methanol via ZnO-SBA-15 supported Cu6 catalyst

Abstract

This study presents a mesoporous material-based catalyst for this reaction, utilizing copper nanoclusters (Cu6) immobilized on Zn-modified SBA-15. The Cu6-ZnO-SBA-15 catalysts are prepared by the wet impregnation of ZnO-SBA-15 with various metal loading contents. Multi-technique characterization shows uniform active phase dispersion within or on the mesoporous SBA-15 channels. The catalytic experiments reveal that the catalyst with the lowest copper content (2 wt.%) exhibits superior activity with a space-time yield of methanol of 232.5 (molMeOH.kgCu-1.h-1)and a selectivity of 86%. Furthermore, the confinement of the active phase into the structure of SBA-15 prevents agglomeration to some extent, implying the excellent stabilization effect of the support. This study highlights the potential of using small nanoclusters prepared by wet chemistry in high-pressure CO2 hydrogenation to methanol.