Issue 5, 2025

Tunnel barriers for Fe-based spin valves providing high spin-polarized current

Abstract

Employing density functional theory for ground state quantum mechanical calculations and the non-equilibrium Green's function method for transport calculations, we investigate the potential of CdS, ZnS, Cd3ZnS4, and Zn3CdS4 as tunnel barriers in magnetic tunnel junctions for spintronics. Based on the finding that the valence band edges of these semiconductors are dominated by pz orbitals and the conduction band edges by s orbitals, we show that Δ1 symmetry filtering of the Bloch states in magnetic tunnel junctions with Fe electrodes results in high tunneling magnetoresistances and high spin-polarized current (up to two orders of magnitude higher than in the case of the Fe/MgO/Fe magnetic tunnel junction).

Graphical abstract: Tunnel barriers for Fe-based spin valves providing high spin-polarized current

Article information

Article type
Paper
Submitted
29 Oct 2024
Accepted
04 Dec 2024
First published
15 Jan 2025
This article is Open Access
Creative Commons BY-NC license

Phys. Chem. Chem. Phys., 2025,27, 2732-2738

Tunnel barriers for Fe-based spin valves providing high spin-polarized current

G. Shukla, H. M. Abdullah and U. Schwingenschlögl, Phys. Chem. Chem. Phys., 2025, 27, 2732 DOI: 10.1039/D4CP04146A

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