Ladder-type 1D coordination polymer of Dy(III): Synthesis and investigation of magnetic behaviours

Abstract

Herein, we report the construction of a H-bonded ladder-type Dy(III) based 1D coordination polymer 1-Dypoly using a 2,6-diacetylpyridine bis-salicyl hydrazone (H4L) ligand system under thermal conditions. The X-ray diffraction studies on the reported coordination polymer revealed that it crystallizes in a monoclinic system having the P21/c space group. The static and dynamic magnetic behavior of 1-Dypoly was investigated using combined experimental and theoretical tools. The zero-field out-of-phase signals for 1-Dypoly were observed, but with fast under-barrier magnetic relaxation processes. CASSCF-based ab initio and BS-DFT calculations were used to rationalize our experimental findings.

Supplementary files

Article information

Article type
Paper
Submitted
12 May 2025
Accepted
05 Jun 2025
First published
08 Jun 2025
This article is Open Access
Creative Commons BY-NC license

CrystEngComm, 2025, Accepted Manuscript

Ladder-type 1D coordination polymer of Dy(III): Synthesis and investigation of magnetic behaviours

N. Ahmed, R. Nabi, X.-G. Zhang and D. J. Darensbourg, CrystEngComm, 2025, Accepted Manuscript , DOI: 10.1039/D5CE00491H

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements