A trigonal arylimido iron complex is reported which is found in an intermediate spin state. The iron bound imido unit is electronically flexible and acts as nucleophile, reductant, or H atom abstractor. The latter is used for catalytic intramolecular C–H bond amination.
A. Gonzalez, A. Casnati, M. Willingshofer, A. Radovic, G. Cutsail III, S. Demeshko, F. Meyer and C. G. Werncke, Chem. Commun., 2025, Accepted Manuscript , DOI: 10.1039/D5CC05205J
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
