SCHEDULED MAINTENANCE:
We developed a Pd-catalyzed Heck/polyfluoroarylation cascade to synthesize polyfluoroarylated oxindoles with all-carbon quaternary centers from alkene-tethered carbamoyl chlorides. The reaction was extended to a three-component one-pot protocol using amines, BTC, and polyfluoroarenes, with preliminary asymmetric results achieved.
C. Chen, Z. Wang, X. Hu, X. Zhang, Y. Zhu, C. Ni and B. Zhu, Chem. Commun., 2025, Accepted Manuscript , DOI: 10.1039/D5CC04604A
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