SCHEDULED MAINTENANCE:
We report herein the synthesis of a tridentate ligand (tris-4,4′,4′′-(4′′′-pyridyl)-2,2′:6′,2′′-terpyridine) and its corresponding homoleptic ruthenium(II) complex, which shows stable hydrogen photoproduction under red light (TON of 174 molH2 molPS−1 after 210 hours). A sustained activity under blue and green lights is also observed with TONs above 360 molH2 molPS−1 after 168 hours.
G. M. Mercier, E. Rousset, I. Oubaha, K. Bandyopadhyay, A. K. Pal, I. Ciofini, L. Chamoreau, V. Marvaud and G. S. Hanan, Chem. Commun., 2025, Advance Article , DOI: 10.1039/D5CC04303D
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