Covalent capture of nitrous oxide by phosphanides
Abstract
Potassium phosphanides with adamantyl or tert-butyl groups form covalent adducts with N2O. The adducts are sufficiently stable to permit crystallographic analyses and reactivity studies.
* Corresponding authors
a
Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland
E-mail:
kay.severin@epfl.ch
Potassium phosphanides with adamantyl or tert-butyl groups form covalent adducts with N2O. The adducts are sufficiently stable to permit crystallographic analyses and reactivity studies.
A. Genoux, T. H. Wong, F. Fadaei-Tirani and K. Severin, Chem. Commun., 2025, 61, 15654 DOI: 10.1039/D5CC04154F
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