SCHEDULED MAINTENANCE:
Three isotopological (stb) mixed-valence iron-formate frameworks， [A][FeIII(FeII)2(HCOO)9] (1-3), were constructed and exhibit ferroelastic phase transition with spontaneous strain of 0.16. 1-3 are spin-canted antiferromagnets with distinct TN from 26 K to 36 K and display exchange bias (EB) performance induced by the pinning of the spins at distinct sublattices.
Q. Yan, S. Han, T. Xu, C. Ji, L. Lv, Z. Q. Yao, J. Zhao and F. Liu, Chem. Commun., 2025, Accepted Manuscript , DOI: 10.1039/D5CC03844H
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