The room-temperature phosphorescence (RTP) properties of corannulene were successfully activated through multi-esterification and phenyl bridging strategies, where the ester groups enhanced spin–orbit coupling (SOC) to facilitate intersystem crossing (ISC), while the phenyl bridges improved RTP efficiency.
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Y. Liu, Z. Gao, X. Wang, W. Lan, M. Gao, T. Tang, Y. Tao, X. Zhao and Y. Yu, Chem. Commun., 2025, 61, 14442 DOI: 10.1039/D5CC03805G
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