A tetraphenylethene-based hexacationic triangular macrocycle (T 6+ •6PF 6 -) was synthesized via the Zincke reaction using anglecontrolled synthesis strategy. Under the chemical or electrochemical reduction conditions, T 6+ •6PF 6 -can undergo twostep reversible and stable redox transformations, accompanied by a distinct visual color change.
Y. Yu, X. Song, Y. Li, P. Wang, L. Cheng, Y. Yang, G. He and L. Cao, Chem. Commun., 2025, Accepted Manuscript , DOI: 10.1039/D5CC03589A
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