Porous MgO-supported Ba–Cs–Ru/MgO catalysts for superior NH3 synthesis and the effect of Ru loading on dispersion of Ru and promoters
Abstract
Porous MgO support through MDCPy is used to prepare superior Ba–Cs–Ru/MgO NH3 synthesis catalysts with better activity than MgO from other methods. Based on the effect of Ru loading on the dispersion of Ru and promoters, the optimal catalyst exhibits a 2.2 nm RuNP@subnano-BaCsOx quasi-core–shell site.