The direct photochemical cross-esterification of alcohols via site-selective C–H bromination

Abstract

We have developed a direct photochemical cross-esterification of alcohols that proceeds via the in situ generation of acyl bromides. The C–H bond of a benzyl alcohol is selectively activated by a bromo source under light irradiation, enabling the cross-esterification to afford a variety of functionalized esters.

Graphical abstract: The direct photochemical cross-esterification of alcohols via site-selective C–H bromination

Supplementary files

Article information

Article type
Communication
Submitted
14 Jun 2025
Accepted
03 Oct 2025
First published
04 Oct 2025
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2025, Advance Article

The direct photochemical cross-esterification of alcohols via site-selective C–H bromination

A. Miyamoto, H. Takamura, I. Kadota and K. Tanaka, Chem. Commun., 2025, Advance Article , DOI: 10.1039/D5CC03371C

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