From the journal:

Chemical Communications

Photoredox mediated one-step syntheses of aryl C-glycosides from unprotected glycosyl sulfinates

Ranadeep Talukdar ORCID logo a  and  Antony J. Fairbanks ORCID logo *a  

* Corresponding authors

a School of Physical and Chemical Sciences, University of Canterbury, Private Bag 4800, Christchurch 8140, New Zealand
E-mail: antony.fairbanks@canterbury.ac.nz

Abstract

Unprotected glycosyl sulfinates undergo Ni-mediated cross coupling with a range of aryl iodides and bromides under photoredox conditions to yield aryl C-glycosides, predominantly as the β-anomers. Thioglycoside formation is occasionally observed as a competitive side reaction.

Graphical abstract: Photoredox mediated one-step syntheses of aryl C-glycosides from unprotected glycosyl sulfinates

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Article information

DOI
https://doi.org/10.1039/D5CC03316K
Article type
Communication
Submitted
11 Jun 2025
Accepted
29 Aug 2025
First published
01 Sep 2025

Chem. Commun., 2025, Advance Article

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Photoredox mediated one-step syntheses of aryl C-glycosides from unprotected glycosyl sulfinates

R. Talukdar and A. J. Fairbanks, Chem. Commun., 2025, Advance Article , DOI: 10.1039/D5CC03316K

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