Tailoring the properties of Sb3+-doped in-based organic–inorganic hybrid metal halides through A-site cation engineering

Ying Qin; Yali Tang; Yue Xiao Pan; Yingnuo Chen; Hongping Xiao; Jun Zou

doi:10.1039/D5CC03205A

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Tailoring the properties of Sb³⁺-doped in-based organic–inorganic hybrid metal halides through A-site cation engineering†

Ying Qin,^a Yali Tang,^a Yue Xiao Pan,

*^a Yingnuo Chen,^a Hongping Xiao*^a and Jun Zou

*^bc

Author affiliations

* Corresponding authors

^a Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, P. R. China
E-mail: yxpan@wzu.edu.com, hp_xiao@wzu.edu.cn

^b Institute of New Materials & Industrial Technology, Wenzhou University, Wenzhou 325024, China

^c School of Science, Shanghai Institute of Technology, Shanghai, China
E-mail: zoujun@sit.edu.cn

Abstract

This study explores how A-site cation engineering and Sb³⁺ doping alter the structure and optical properties of two zero-dimensional (0D) organic–inorganic hybrid metal halides (OIHMHs). Incorporating C₄H₁₀SN⁺ (TMPL = protonated thiomorpholine) into (Ph₃S)₂InCl₅:Sb³⁺ (Ph₃S = triphenylsulfonium cation) forms (Ph₃S)(TMPL)₂InCl₆:Sb³⁺, causing a blue-shift in emission from orange-red to yellow.

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Article information

DOI: https://doi.org/10.1039/D5CC03205A
Article type: Communication
Submitted: 06 Jun 2025
Accepted: 16 Jul 2025
First published: 17 Jul 2025

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Chem. Commun., 2025, Advance Article

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Tailoring the properties of Sb³⁺-doped in-based organic–inorganic hybrid metal halides through A-site cation engineering

Y. Qin, Y. Tang, Y. X. Pan, Y. Chen, H. Xiao and J. Zou, Chem. Commun., 2025, Advance Article , DOI: 10.1039/D5CC03205A

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