Redox-associated phase transition of a marginally stable synthetic polymer

Abstract

We elucidated the stimuli-responsive phase transition in a synthetic model of marginally stable proteins composed of poly(N-isopropylacrylamide) with incorporated redox-responsive sites. Redox-state changes in a single redox-responsive site were efficiently converted to hydration and dehydration of multiple monomer units within the polymer chain synchronized with electron transfer.

Graphical abstract: Redox-associated phase transition of a marginally stable synthetic polymer

Supplementary files

Article information

Article type
Communication
Submitted
23 May 2025
Accepted
09 Jul 2025
First published
10 Jul 2025

Chem. Commun., 2025, Advance Article

Redox-associated phase transition of a marginally stable synthetic polymer

T. Enomoto, K. Terui, S. Yagi, A. M. Akimoto and R. Yoshida, Chem. Commun., 2025, Advance Article , DOI: 10.1039/D5CC02924D

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