A non-innocent, π-extended N-Heterobicyclic Carbene-thiolate ligand

Abstract

A bidentate NHC-thiolate ligand based on the imidazo[1,5-a]pyridine scaffold and featuring an extended π-system is described. It is derived from a readily available zwitterionic precursor and the chemistry of the corresponding homoleptic Ni(II) complex is investigated.

Supplementary files

Article information

Article type
Communication
Submitted
19 May 2025
Accepted
16 Jun 2025
First published
23 Jun 2025
This article is Open Access
Creative Commons BY license

Chem. Commun., 2025, Accepted Manuscript

A non-innocent, π-extended N-Heterobicyclic Carbene-thiolate ligand

M. Marquardt, L. Vendier, A. Saquet, V. Maurel, J. Mouesca, S. BASTIN, I. Castillo and V. Cesar, Chem. Commun., 2025, Accepted Manuscript , DOI: 10.1039/D5CC02841H

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