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Chemical Communications

Lanthanide Complexes of Aminopolycarboxylates Reveal Deuteration of Aminoacetate Carbons In Alkaline Aqueous Media

Sebastian Friedrich,   Lukas Waurick,   Björn Drobot,   Robin Steudtner,   Katharina Müller,   Astrid Barkleit,   Thorsten Stumpf  and  Jerome Kretzschmar  

Abstract

Hydrogen isotope exchange at aminoacetate carbons is facilitated in lanthanide aminopolycarboxylate complexes in NaOD D2O solution. Ionic radius-dependent yields revealed Lu3+ being choice. NMR and Raman spectroscopies evidence yield and selectivity while theoretical calculations help understanding the mechanism.

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DOI
https://doi.org/10.1039/D5CC02730F
Article type
Communication
Submitted
14 May 2025
Accepted
10 Jul 2025
First published
14 Jul 2025
This article is Open Access
Creative Commons BY license

Chem. Commun., 2025, Accepted Manuscript

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Lanthanide Complexes of Aminopolycarboxylates Reveal Deuteration of Aminoacetate Carbons In Alkaline Aqueous Media

S. Friedrich, L. Waurick, B. Drobot, R. Steudtner, K. Müller, A. Barkleit, T. Stumpf and J. Kretzschmar, Chem. Commun., 2025, Accepted Manuscript , DOI: 10.1039/D5CC02730F

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