Issue 57, 2025
From the journal:

Chemical Communications

Synthesis and isolation of less stable cyclopropene-1-carboxylates†

Jiahao Ling,‡a   Jiabao Tian,‡a   Xinhai Zhu*b  and  Lei Zhou ORCID logo *a  

* Corresponding authors

a Institute of Green Chemistry and Molecular Engineering, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China
E-mail: zhoul39@mail.sysu.edu.cn

b Instrumental Analysis & Research Center, Sun Yat-sen University, Guangzhou, China
E-mail: zhuxinh@mail.sysu.edu.cn

Abstract

Less stable acceptor-type cyclopropenes are prepared and isolated via blue light-promoted photolysis of vinyldiazo compounds. The kinetic measurements indicated that their half-lives were influenced by the concentration, temperature and solvent.

Graphical abstract: Synthesis and isolation of less stable cyclopropene-1-carboxylates

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Article information

DOI
https://doi.org/10.1039/D5CC02673C
Article type
Communication
Submitted
11 May 2025
Accepted
09 Jun 2025
First published
10 Jun 2025

Chem. Commun., 2025,61, 10566-10569

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Synthesis and isolation of less stable cyclopropene-1-carboxylates

J. Ling, J. Tian, X. Zhu and L. Zhou, Chem. Commun., 2025, 61, 10566 DOI: 10.1039/D5CC02673C

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