π-Extension from a diquinoxaline-fused pyrene led to a twisted azananographene (azaNG) exhibiting red emission. Although the azaNG was highly contorted, the electronic nature of the diquinoxaline-fused pyrene was confirmed to be retained, and thus it exhibited three-electron accepting ability as well as a low-lying LUMO level.
Z. Zhang, Z. Xu, A. Zhang, F. Bai, Y. Hashikawa and Chaolumen, Chem. Commun., 2025, 61, 11401 DOI: 10.1039/D5CC02120K
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