Donor-Acceptor Semiconducting Polymers as Superior Photocatalysts in Homogeneous Phase and Recycled via Antisolvent Precipitation Strategy

Abstract

Donor-acceptor conjugated polymer PBDT-AQ outperformed PBDT-AM in homogeneous photocatalytic oxidation of phenyl methyl sulfides and phenylboronic acids with excellent yields due to superior oxygen adsorption and lower charge transfer resistance along with excellent solubility in suitable solvents, strong visible-light absorption, optimal band gaps, and appropriate LUMO levels, and are recycled over five times by heterogenization via antisolvent precipitation method.

Supplementary files

Article information

Article type
Communication
Submitted
02 Apr 2025
Accepted
23 May 2025
First published
26 May 2025

Chem. Commun., 2025, Accepted Manuscript

Donor-Acceptor Semiconducting Polymers as Superior Photocatalysts in Homogeneous Phase and Recycled via Antisolvent Precipitation Strategy

S. Manna, K. Maity, F. Banerjee, S. Sau and S. K. Samanta, Chem. Commun., 2025, Accepted Manuscript , DOI: 10.1039/D5CC01869B

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