Interfacial Cation Engineering in δ-MnO₂ Nanosheets for Efficient Oxygen Reduction Reaction

Abstract

The cationic effect on δ-MnO2 nanosheets for oxygen reduction reaction (ORR) is investigated by intercalating different interfacial cations (Li, Cs, diallyldimethylammonium (DADMA) and polydimethyl diallyl ammonium (PDDA)). Experimental and theoretical analyses demonstrate that interfacial cations can modulate the catalytic activity by tailoring the electronic structure and spatial water molecules distribution between δ-MnO2 nanosheets.

Supplementary files

Article information

Article type
Communication
Submitted
02 Apr 2025
Accepted
06 May 2025
First published
06 May 2025

Chem. Commun., 2025, Accepted Manuscript

Interfacial Cation Engineering in δ-MnO₂ Nanosheets for Efficient Oxygen Reduction Reaction

D. Wu, H. Wan, Z. Zheng, C. Kuang, N. Zhang, G. Chen, X. Liu and R. Ma, Chem. Commun., 2025, Accepted Manuscript , DOI: 10.1039/D5CC01863C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements