Issue 51, 2025

An unexpected chlorination of an organic sunscreen

Abstract

The origin of intense red staining on fabrics contaminated by sunscreen and treated with bleach has been attributed to an unexpected dichlorination of a common UV filter. The structure of the chromophore has been determined by NMR spectroscopy, and the proposed mechanism of its formation is supported by DFT calculations.

Graphical abstract: An unexpected chlorination of an organic sunscreen

Supplementary files

Article information

Article type
Communication
Submitted
20 Mar 2025
Accepted
20 May 2025
First published
21 May 2025
This article is Open Access
Creative Commons BY license

Chem. Commun., 2025,61, 9314-9317

An unexpected chlorination of an organic sunscreen

L. G. Smith, D. Di Leva, L. A. Shaw, E. Hughes, A. M. Kenwright, A. Beeby, M. R. Wilson and C. S. Mahon, Chem. Commun., 2025, 61, 9314 DOI: 10.1039/D5CC01593F

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