Orthogonal decoupling of an ionic-electronic transport microarchitectured vertical array cathode for flexible sodium-ion batteries†
Abstract
Vertically-aligned Na3V2O2(PO4)2F cathodes with orthogonal ion/electron pathways exhibit enhanced Na+ diffusion (5.8 × 10−12 m2 s−1), delivering 131 mA h g−1 at 0.2C, 85 mA h g−1 at 5C, and 96% capacity retention after 1000 cycles for flexible energy storage.