Visible-light organophotoredox-catalyzed fluoroalkyl aminoxylation of unactivated and activated alkenes

Jianhua Ji; Kangjie Li; Xiangzhu Zhou; Chun Xu; Die Zhang; Wen Shao

doi:10.1039/D5CC00748H

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Visible-light organophotoredox-catalyzed fluoroalkyl aminoxylation of unactivated and activated alkenes†

Jianhua Ji,‡^a Kangjie Li,‡^a Xiangzhu Zhou,^a Chun Xu,^a Die Zhang^a and Wen Shao

*^a

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* Corresponding authors

^a Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105, P. R. China
E-mail: shaowen@xtu.edu.cn

Abstract

An efficient method for the regioselective tetra-, tri-, di- and per-fluoroalkyl aminoxylation of unactivated and activated alkenes has been achieved with various fluorinated alkyl halides and OH-hydroxylamines. This developed photoredox-neutral protocol features versatile transformations to novel tetrafluoroethylene-containing compounds.

This article is part of the themed collection: 2025 Emerging Investigators

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DOI: https://doi.org/10.1039/D5CC00748H
Article type: Communication
Submitted: 11 Feb 2025
Accepted: 02 Apr 2025
First published: 03 Apr 2025

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Chem. Commun., 2025, Advance Article

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Visible-light organophotoredox-catalyzed fluoroalkyl aminoxylation of unactivated and activated alkenes

J. Ji, K. Li, X. Zhou, C. Xu, D. Zhang and W. Shao, Chem. Commun., 2025, Advance Article , DOI: 10.1039/D5CC00748H

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Chemical Communications

Visible-light organophotoredox-catalyzed fluoroalkyl aminoxylation of unactivated and activated alkenes†

Abstract

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Visible-light organophotoredox-catalyzed fluoroalkyl aminoxylation of unactivated and activated alkenes

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