From the journal:

Chemical Communications

A dual-radical process for tri/di-fluoromethylarylation of alkenes enabled by indirect electroreduction†

Zhening Jin,a   Yuan Shi,a   Zhangchi Zheng,a   Yuxin Ding,a   Weike Su,a   Changjun Zhang*a  and  YuanYuan Xie ORCID logo *abc  

* Corresponding authors

a College of Pharmaceutical Science, Zhejiang University of Technology, Hangzhou, People's Republic of China
E-mail: xyycz@zjut.edu.cn, zhangchangjun@zjut.edu.cn

b Collaborative Innovation Center of Yangtze River Delta Region Green Pharmaceuticals, Zhejiang University of Technology, Hangzhou, People's Republic of China

c Key Laboratory for Green Pharmaceutical Technologies and Related Equipment of Ministry of Education, Key Laboratory of Pharmaceutical Engineering of Zhejiang Province, Hangzhou, People's Republic of China

Abstract

This study presents a stable and mild electrochemical dual-radical strategy for tri/di-fluoromethylarylation of alkenes. The synergistic combination of cyanoarene and phenanthrene as dual redox mediators constructs an efficient catalytic system.

Graphical abstract: A dual-radical process for tri/di-fluoromethylarylation of alkenes enabled by indirect electroreduction

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Article information

DOI
https://doi.org/10.1039/D5CC00744E
Article type
Communication
Submitted
12 Feb 2025
Accepted
10 Apr 2025
First published
10 Apr 2025

Chem. Commun., 2025, Advance Article

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A dual-radical process for tri/di-fluoromethylarylation of alkenes enabled by indirect electroreduction

Z. Jin, Y. Shi, Z. Zheng, Y. Ding, W. Su, C. Zhang and Y. Xie, Chem. Commun., 2025, Advance Article , DOI: 10.1039/D5CC00744E

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