Issue 29, 2025
From the journal:

Chemical Communications

Intrinsic stimuli-responsive main-chain supramolecular polymers driven by dative B ← N bonds†

Xupeng Ji,‡a   Zihao Wang,‡a   Wei Yuan,b   Zhao Gao ORCID logo *a  and  Wei Tian ORCID logo *a  

* Corresponding authors

a Shaanxi Key Laboratory of Macromolecular Science and Technology, Xi’an Key Laboratory of Hybrid Lumines-cent Materials and Photonic Device, MOE Key Laboratory of Material Physics and Chemistry under Extraordinary Conditions, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi’an, China
E-mail: gaozhao@nwpu.edu.cn, happytw_3000@nwpu.edu.cn

b Department of Chemistry, National University of Singapore 3 Science Drive 3, Singapore 117543, Singapore

Abstract

Novel main-chain supramolecular polymers (MCSPs) with intrinsic stimuli-responsiveness were developed using dative B ← N bonds. By separately fluoridating/defluoridating boron and protonating/deprotonating nitrogen, the resultant MCSPs show reversible intrinsic response.

Graphical abstract: Intrinsic stimuli-responsive main-chain supramolecular polymers driven by dative B ← N bonds

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Article information

DOI
https://doi.org/10.1039/D5CC00379B
Article type
Communication
Submitted
21 Jan 2025
Accepted
09 Mar 2025
First published
10 Mar 2025

Chem. Commun., 2025,61, 5447-5450

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Intrinsic stimuli-responsive main-chain supramolecular polymers driven by dative B ← N bonds

X. Ji, Z. Wang, W. Yuan, Z. Gao and W. Tian, Chem. Commun., 2025, 61, 5447 DOI: 10.1039/D5CC00379B

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