A mixed-metal PtIIRhI2 trinuclear complex with triply bridging sulfide ligands, generated by the reaction of a Rh(I) nbd complex with a bis(hydrosulfido) Pt(II) complex bearing a bisNHC ligand, is oxidised under aerobic conditions to give a diamagnetic hexanuclear cluster accompanied by the formation of a RhII–RhII bond.
A. Yokoyama, H. Nakajima and T. Nishioka, Chem. Commun., 2025, 61, 4523 DOI: 10.1039/D5CC00112A
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