Uncommon quadruple stacking topology in a honeycomb-sheet MOF compatible with through-space conduction

Tappei Tanabe; Liyuan Qu; Kenta Ueno; Shinya Takaishi; Masahiro Yamashita; Yuh Hijikata; Ryotaro Matsuda; Ryota Sakamoto; Hiroaki Iguchi

doi:10.1039/D5CC00084J

Uncommon quadruple stacking topology in a honeycomb-sheet MOF compatible with through-space conduction†

Tappei Tanabe,

^ab Liyuan Qu,

^b Kenta Ueno,^a Shinya Takaishi,

^a Masahiro Yamashita,

^ac Yuh Hijikata,

^d Ryotaro Matsuda,

^b Ryota Sakamoto

^a and Hiroaki Iguchi

*^b

Author affiliations

* Corresponding authors

^a Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-ku, Sendai, Miyagi 980-8578, Japan

^b Department of Materials Chemistry, Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan
E-mail: hiroaki.iguchi@chembio.nagoya-u.ac.jp

^c School of Chemical Science and Engineering, Tongji University, Shanghai 559 200092, P. R. China

^d Research Center for Net Zero Carbon Society, Institutes of Innovation for Future Society, Nagoya University, Chikusa-ku, Nagoya 464-8601, Japan

Abstract

Quadruple stacking topology with an unusual threefold stacking periodicity in four honeycomb sheets was realized in a flexible wavy honeycomb-sheet MOF (PMC-20). The infinite π-stacked arrays, formed exclusively at the π-conjugated core of the linker site, contribute to the highest electrical conductivity among the reported naphthalenediimide (NDI)-based crystals.

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DOI: https://doi.org/10.1039/D5CC00084J
Article type: Communication
Submitted: 06 Jan 2025
Accepted: 20 May 2025
First published: 22 May 2025
This article is Open Access

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Chem. Commun., 2025, Advance Article

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Uncommon quadruple stacking topology in a honeycomb-sheet MOF compatible with through-space conduction

T. Tanabe, L. Qu, K. Ueno, S. Takaishi, M. Yamashita, Y. Hijikata, R. Matsuda, R. Sakamoto and H. Iguchi, Chem. Commun., 2025, Advance Article , DOI: 10.1039/D5CC00084J

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Chemical Communications

Uncommon quadruple stacking topology in a honeycomb-sheet MOF compatible with through-space conduction†

Abstract

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Uncommon quadruple stacking topology in a honeycomb-sheet MOF compatible with through-space conduction

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