C(sp3)–H bond nitration provides facile access to nitro compounds that are inaccessible through traditional nitration pathways. This work describes a C(sp3)–H bond nitration of aryl alkenes using DNDMH, a nitration reagent developed previously in our lab. Notably, this novel nitration process presents excellent regioselectivity and chemoselectivity between C(sp3)–H nitration and C(sp2)–H nitration.
Z. Wang, Y. Li, X. Ding, Y. Sun, C. Chen, W. Sun and X. Hu, Chem. Commun., 2025, 61, 3147 DOI: 10.1039/D4CC06671E
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