Synthesis and characterization of triazole-functionalized mixed-valent Si(i)–Si(iii) and bis(germylene) compounds†
Madhusudan K.
Pandey, 
a
Mukesh K.
Singh,
*b
Regine
Herbst-Irmer,
a
Dietmar
Stalke,
*a
Pattiyil
Parameswaran
*c
and
Herbert W.
Roesky
*a
a
Mukesh K.
Singh,
*b
Regine
Herbst-Irmer,
a
Dietmar
Stalke,
*a
Pattiyil
Parameswaran
*c
and
Herbert W.
Roesky
*a
Abstract
The synthesis of mixed-valent main-group compounds is a challenging goal that has attracted significant interest recently. The reaction of 1-(2-bromophenyl)-4-phenyl-1H-1,2,3-triazole with nBuLi, followed by treatment with [(PhC(tBuN)2SiCl)], yielded a rare Si(I)–Si(III) compound (1), whereas treatment with [(PhC(tBuN)2GeCl)] produced a bis(germylene) compound (2).
Please wait while we load your content...
