Solvent-controlled silver catalyzed radical transformation of α-imino-oxy acids with cyclic aldimines

Jingjing Wang; Yuran Qin; Ke Cui; Xueqi Li; Mingyue Cui; Sheng Cao; Linbo Zhang; Qin Shen; Teng Wang; Feng Li

doi:10.1039/D4CC05675B

Solvent-controlled silver catalyzed radical transformation of α-imino-oxy acids with cyclic aldimines†

Jingjing Wang,^a Yuran Qin,^a Ke Cui,^a Xueqi Li,^a Mingyue Cui,^a Sheng Cao,

^a Linbo Zhang,^a Qin Shen,^c Teng Wang

*^b and Feng Li

*^a

Author affiliations

* Corresponding authors

^a Lunan Institute of Intelligent Biomedical Engineering, College of Food Science and Pharmaceutical Engineering, Zaozhuang University, Zaozhuang, P. R. China
E-mail: lifeng20150720@163.com

^b College of Chemistry, Beijing University of Chemical Technology, Beijing, P. R. China
E-mail: wangt@mail.buct.edu.cn

^c Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China

Abstract

A silver-catalyzed cross coupling of cyclic aldimines and α-imino-oxy acids has been developed. The solvent-dependent reaction could selectively deliver either cyclic imine moiety retained nitriles or ring-opened oxonitriles in moderate yields. The mechanistic studies show that the reaction undergoes a radical pathway.

Chemical Communications

Solvent-controlled silver catalyzed radical transformation of α-imino-oxy acids with cyclic aldimines†

Abstract

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Solvent-controlled silver catalyzed radical transformation of α-imino-oxy acids with cyclic aldimines

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