Issue 23, 2024

Facile synthesis of naphthalene-based porous organic salts for photocatalytic oxidative coupling of amines in air

Abstract

In this report, a new naphthalene-based porous organic salt (NA-POS-1) was synthesized by a facile self-assembly of two sulfonic acid and amine functionalized naphthalene-based building blocks by strong ionic and hydrogen bonding interactions. The obtained NA-POS-1 possesses a crystalline structure, nano-/microrod morphology, considerable porosity and extended naphthalene-based π-conjugated system. Very interestingly, the clever combination of these two naphthalene-based building blocks (NDA and NDSA) endows NA-POS-1 with strong visible-light-harvesting ability and excellent photo-induced charge transfer capability. Therefore, such a π-conjugated organic salt, NA-POS-1, was first regarded as an efficient heterogeneous photocatalyst for visible-light-driven photocatalytic oxidative coupling of amines with O2 from atmospheric air by virtue of the generated reactive oxygen species, superoxide radical anions, which provides a promising photocatalyst for photocatalytic oxidation reactions. This work provides a new direction for the facile synthesis of more photoactive porous organic salts by combining various π-conjugated organic building blocks for diverse photocatalytic reactions.

Graphical abstract: Facile synthesis of naphthalene-based porous organic salts for photocatalytic oxidative coupling of amines in air

Supplementary files

Article information

Article type
Paper
Submitted
06 Mar 2024
Accepted
08 May 2024
First published
09 May 2024

J. Mater. Chem. A, 2024,12, 14159-14166

Facile synthesis of naphthalene-based porous organic salts for photocatalytic oxidative coupling of amines in air

S. Wang, J. Chen, Y. Chang, S. Wang, C. Meng, Z. Long and G. Chen, J. Mater. Chem. A, 2024, 12, 14159 DOI: 10.1039/D4TA01548G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements