Issue 10, 2024

Effect of defects and framework Sn on the stability and activity of Pt clusters for ethane dehydrogenation in chabazite zeolite

Abstract

With increasing interest in new catalytic materials based on atomically dispersed transition metals on various supports (e.g., zeolites or oxides), it is necessary to have an atomic level understanding of the factors that determine their structural and electronic properties as well as catalytic activity. Encapsulated Pt atoms and sub-nanometer Pt clusters in Sn-substituted zeolitic frameworks have demonstrated extended catalytic stability and remarkable selectivity for alkane dehydrogenation to alkenes. Despite efforts to characterize these materials, the bonding environment of the dispersed atoms in the presence of framework Sn or of defect silanols is uncertain. We have employed ab initio molecular dynamics simulations and electronic structure calculations to identify and characterize electronically stable Pt active site motifs in chabazite (CHA) and Sn-CHA at low Pt loadings. The activity of several active site motifs was assessed by microkinetic simulations. We demonstrate that framework Sn and silanol defects can promote the dispersion of Pt species. Unexpectedly, we find that in the presence of silanol nests, the dispersed Pt species statistically prefer to coordinate with the silanols and not with the framework Sn. We show that Pt and Sn are bonded via a 3-center-4-electron bond (O:–Sn–:Pt), affirm the absence of Pt–O–Sn bonding, and thus resolve the ambiguity related to the coordination of Pt to framework Sn. We predict that the O:–Sn–:Pt and Sn–O–Pt–Pt–Si bonding motifs in Sn-CHA are stable and active for ethane dehydrogenation. We relate our findings and conclusions to recent experimental characterization of Pt in Sn-BEA zeolite, point out the close alignment in several aspects and suggest that the effect of framework Sn on the dispersion of low nuclearity Pt species and on the formation of stable and efficient active sites should be largely independent of the framework itself.

Graphical abstract: Effect of defects and framework Sn on the stability and activity of Pt clusters for ethane dehydrogenation in chabazite zeolite

Supplementary files

Article information

Article type
Paper
Submitted
08 Apr 2024
Accepted
03 Aug 2024
First published
06 Aug 2024
This article is Open Access
Creative Commons BY-NC license

React. Chem. Eng., 2024,9, 2784-2793

Effect of defects and framework Sn on the stability and activity of Pt clusters for ethane dehydrogenation in chabazite zeolite

S. Srinivas, D. G. Vlachos and S. Caratzoulas, React. Chem. Eng., 2024, 9, 2784 DOI: 10.1039/D4RE00187G

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