Structural and luminescence properties of novel Eu3+-doped Na3Ba2LaNb10O30 phosphors with high quantum efficiency and excellent color purity for w-LED applications

Abstract

In this study, we report the successful synthesis and thorough characterization of Eu³⁺-doped Na₃Ba₂LaNb₁₀O₃₀ phosphors, targeting their application in white-light-emitting diodes (w-LEDs). The phosphors were synthesized using a high-temperature solid-state method, ensuring robust incorporation of Eu³⁺ ions into the host lattice. Comprehensive analyses were performed, including X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray (EDX) spectroscopy, Fourier transform infrared (FT-IR) spectroscopy and Raman spectroscopy, confirming the phase purity, crystallinity, morphology, and elemental composition of the phosphors. We have also studied the electronic structure using diffuse reflectance spectroscopy (DRS). Photoluminescence studies revealed strong red emissions under near-ultraviolet light excitation, with the optimal Eu³⁺ doping concentration identified to be 9 mol%. Quantum-yield measurements demonstrated high luminescence efficiency, while chromaticity coordinates indicated excellent color purity suitable for w-LED applications. These findings contribute significantly to the advancement of phosphor materials for solid-state lighting, suggesting promising prospects for their integration into commercial LED devices.