Aidan E. Izuagbe, Bryan T. Tuten, Peter W. Roesky and Christopher Barner-Kowollik
Polym. Chem., 2024,15, 1955-1961
DOI:
10.1039/D4PY00280F,
Paper
We introduce a light-driven methodology (λmax = 365 nm) to fold single polymer chains into single chain nanoparticles (SCNPs). Exploiting the photo-isomerization of spiropyran entities embedded into the backbone of polymer chains (ranging from 15 to 38 mol%) constituted of polyethylene glycol carrying monomer units (ranging from Mn = 28 500 g mol−1 to 40 000 g mol−1), we complex their open form using a range of metals, including iron, copper and cobalt. The approach offers the first direct avenue for incorporating metals into SCNPs via a photochemical folding mechanism in one step.