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Herein, a electroreductive carboxylation of benzylphosphonium salts was achieved by the cleavage of the C(sp3)–P bond, and various valuable arylacetic acids could be synthesized by this strategy. Also, based on control experiments and previous studies, a plausible reaction mechanism was proposed to explain the reaction process. The establishment of this procedure will provide a new paradigm for the functionalization of alkyl phosphonium salts.

Graphical abstract: Electroreductive carboxylation of benzylphosphonium salts with CO2 through the cleavage of the C(sp3)–P bond

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