This study demonstrates the successful formation of a radical anion intermediate in a moist atmosphere, facilitating chemical reactions by activating aerial dioxygen through a single electron transfer (SET) mechanism. Derived from deprotonating quinoxaline-2(1H)-one with KOtBu, it shows potential in oxygenation chemistry. Validation comes from radical scavenging and EPR experiments.
To support increased transparency, we offer authors the option to publish the peer review history alongside their article.
S. Sau, S. Sahoo, A. Manna and P. Mal, Org. Biomol. Chem., 2024, 22, 4662 DOI: 10.1039/D4OB00673A
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
