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Tosyl cyanide is a commonly used reagent for cyanation and sulfonylation in organic synthesis and pharmaceutical chemistry. The photocatalytic transformations of tosyl cyanide are generally conducted under mild conditions. This minireview summarizes the recent progress of radical-involved transformations of tosyl cyanide via photo-induced cyanation or sulfonylcyanation.

Graphical abstract: Photo-induced radical transformations of tosyl cyanide

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