We report an aniline ligand (1) with two bis(pyrazolyl)alkane arms, and its cationic, dizinc complexes. XRD, NMR, and modelling of the dizinc complexes resulted in an unprecedented, dynamic μ-anilide core. Compared with published μ-phenolate analogues, our μ-anilide complexes show higher activity and divergent counterion trends in ring-opening polymerization of rac-lactide.
P. K. Naik, Z. Gu and R. J. Comito, Dalton Trans., 2024, 53, 17443 DOI: 10.1039/D4DT02837F
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