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Abstract | Cited by

The first anionic pentacoordinated group 14 compounds bearing a phenylethynyl substituent were successfully synthesized and crystallographically characterized. The synthesized ate-type compounds were stable in air, water, and some acids, allowing their application as reagents for the nucleophilic alkynylation of carbon electrophiles.

Graphical abstract: Synthesis, structure, and alkynylation reactivity of alkynyl-silicate, -germanate, and -stannate

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