Issue 29, 2024

High ionic conduction in a robust anionic metal–organic framework containing Mg2+ under guest vapors

Abstract

We report on the synthesis and high ionic conductivity of a highly crystalline Mg2+-containing metal–organic framework (MOF) with Type A feature (i.e., anionic framework having Mg2+ as a counter cation). We synthesized Mg[Zr(C14H3O8)2] (SU-102-Mg) through ion exchange reaction. SU-102-Mg showed a high ionic conductivity of 3.6 × 10−5 S cm−1 (25 °C, under MeCN vapor).

Graphical abstract: High ionic conduction in a robust anionic metal–organic framework containing Mg2+ under guest vapors

Supplementary files

Article information

Article type
Communication
Submitted
06 May 2024
Accepted
23 Jun 2024
First published
15 Jul 2024
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2024,53, 12043-12046

High ionic conduction in a robust anionic metal–organic framework containing Mg2+ under guest vapors

S. Niwa, S. Hashimoto, D. Chen, T. Toyao, K. Shimizu and M. Sadakiyo, Dalton Trans., 2024, 53, 12043 DOI: 10.1039/D4DT01331J

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