A synthesis of iminopyridines based on zinc has been developed. The commercially available ZnEt2 was employed as a precatalyst for this process. A mechanism has been proposed on the basis of Density Functional Theory (DFT) studies and stoichiometric reactions. The zinc amidinato intermediates underscore the critical role of zinc in this synthesis process.
B. Parra-Cadenas, C. Ginés, D. García-Vivó, D. Elorriaga and F. Carrillo-Hermosilla, Dalton Trans., 2024, 53, 10050 DOI: 10.1039/D4DT01265H
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