Issue 22, 2024
From the journal:

Dalton Transactions

Generation and study of Am(iv) by temperature-controlled electron pulse radiolysis†

Amy E. Kynman, ORCID logo *ab   Travis S. Grimes, ORCID logo a   Stephen P. Mezyk,c   Bobby Layne,d   Andrew R. Cook, ORCID logo d   Brian M. Rotermunde  and  Gregory P. Horne ORCID logo *a  

* Corresponding authors

a Center for Radiation Chemistry Research, Idaho National Laboratory, Idaho Falls, ID, USA
E-mail: gregory.holmbeck@inl.gov

b Glenn T. Seaborg Institute, Idaho National Laboratory, Idaho Falls, ID, USA
E-mail: amy.kynman@inl.gov

c Department of Chemistry and Biochemistry, California State University Long Beach, Long Beach, CA 90840, USA

d Department of Chemistry, Brookhaven National Laboratory, Upton, New York, USA

e Department of Chemistry, Colorado School of Mines, Golden, Colorado 80401, USA

Abstract

First-of-a-kind temperature-controlled electron pulse radiolysis experiments facilitated the radiation-induced formation of Am(IV) in concentrated (6.0 M) HNO3, and enabled the derivation of Arrhenius and Eyring activation parameters for instigating the radical reaction between NO3˙ and Am(III).

Graphical abstract: Generation and study of Am(iv) by temperature-controlled electron pulse radiolysis

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Article information

DOI
https://doi.org/10.1039/D4DT00991F
Article type
Communication
Submitted
04 Apr 2024
Accepted
09 May 2024
First published
22 May 2024

Dalton Trans., 2024,53, 9262-9266

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Generation and study of Am(IV) by temperature-controlled electron pulse radiolysis

A. E. Kynman, T. S. Grimes, S. P. Mezyk, B. Layne, A. R. Cook, B. M. Rotermund and G. P. Horne, Dalton Trans., 2024, 53, 9262 DOI: 10.1039/D4DT00991F

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