Magnetic anisotropy in octahedral Dy(iii) and Yb(iii) complexes†
Aditya
Borah, 
ac
Sourav
Dey,
a
Kehkasha
Siddiqui,
a
Sandeep K.
Gupta,
b
Gopalan
Rajaraman
*a
and
Ramaswamy
Murugavel
*a
ac
Sourav
Dey,
a
Kehkasha
Siddiqui,
a
Sandeep K.
Gupta,
b
Gopalan
Rajaraman
*a
and
Ramaswamy
Murugavel
*a
Abstract
New organophosphate complexes [Ln(dippH)3(dippH2)3]·(H2O)6, (Ln = Dy, Yb and Y; dippH2 = 2,6-diisopropylphenyl phosphate), displaying octahedral coordination geometry around the metal ion, exhibit unusual slow relaxation of magnetisation, which is investigated through experimental studies and ab initio CASSCF calculations.
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