Issue 8, 2024
From the journal:

Dalton Transactions

Interconversion between multicomponent slider-on-deck and palladium capsule: regulation of catalysis and encapsulation†

Isa Valiyev, ORCID logo a   Indrajit Paul,a   Yi-Fan Li,a   Emad Elramadi ORCID logo a  and  Michael Schmittel ORCID logo *a  

* Corresponding authors

a Center of Micro and Nanochemistry and (Bio)Technology, Organische Chemie I, School of Science and Engineering, Universität Siegen, Adolf-Reichwein-Str. 2, D-57068 Siegen, Germany
E-mail: schmittel@chemie.uni-siegen.de

Abstract

When the slider-on-deck [Cu3(1)(2)]3+ and guest G were treated with palladium(II) ions, the biped 2 was released from [Cu3(1)(2)]3+ generating the nanocage [Pd2(2)4(G)]4+ with guest G being encapsulated (NetState-II). This transformation that was reversed by the addition of DMAP enabled modulation of both the overall fluorescence and the activity of copper(I) catalyzing an aza Hopf cyclization.

Graphical abstract: Interconversion between multicomponent slider-on-deck and palladium capsule: regulation of catalysis and encapsulation

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Article information

DOI
https://doi.org/10.1039/D3DT04300B
Article type
Communication
Submitted
21 Dec 2023
Accepted
25 Jan 2024
First published
02 Feb 2024
This article is Open Access
Creative Commons BY license

Dalton Trans., 2024,53, 3454-3458

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Interconversion between multicomponent slider-on-deck and palladium capsule: regulation of catalysis and encapsulation

I. Valiyev, I. Paul, Y. Li, E. Elramadi and M. Schmittel, Dalton Trans., 2024, 53, 3454 DOI: 10.1039/D3DT04300B

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