Excitation of long-lived nuclear spin order using spin-locking: a geometrical formalism

Abstract

Over the last two decades, numerous pulse sequences have been introduced for the excitation of long-lived spin order (LLS) in high fields. The long continuous wave (CW) or adiabatic pulses used in the SLIC and APSOC sequences should remind one of the spin-locking pulses that are used to induce cross-polarization (CP). Dynamics during these spin-lockings in CP experiments are explained through a geometrical formalism. However, the SLIC and APSOC sequences are described in terms of the energy-level picture or in the language of level anti-crossings. Motivated by this analogy, this work presents here a geometrical formalism for the LLS excitation by spin-locking pulses in weakly coupled systems. The formalism is similar to the one used for CP dynamics and reveals new pulse sequences involving CW or adiabatic locking. A similar formalism for the sustaining period of LLS is also provided, which reveals new features of the dynamics and suggests the usage of modulated spin-lockings for proper LLS sustaining. For strong and intermediate regimes, although a simple geometrical formalism seems infeasible, a new pulse sequence that employs a ramp-down adiabatic pulse for both LLS excitation and reconversion to observables in both these regimes is presented here. Given the similarities between LLS excitation and well-developed CP, it may be anticipated that this work would initiate the search for new LLS excitation methods and applications.